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oxidation state of phosphorus solid

Join now. If you look at the periodic table, you will see that phosphorus is in the 15th column. The oxidation of phosphorus by sulfur at low temperatures (<100 °C) has been shown to produce complex mixtures that include 12 of the 17 known binary phosphorus sulfides. What is the oxidation state of an individual phosphorus atom in po33-? Need an editable periodic table to edit? Phosphorus forms two common oxides, phosphorus(III) oxide (or tetraphosphorus hexoxide), P 4 O 6, and phosphorus(V) oxide (or tetraphosphorus decaoxide), P 4 O 10.Both oxides have a structure based on the tetrahedral structure of elemental white phosphorus. Elemental phosphorus (oxidation state 0) does. In nitrogen, the oxidation states from +1 to +4 tend to disproportionate in acidic solution. Phosphorus Regulated Cobalt Oxide@Nitrogen‐Doped Carbon Nanowires for Flexible Quasi‐Solid‐State Supercapacitors. 45. Contrary to simple insertion electrochemical reactions, e.g., of Prussian blue and similar compounds, the reaction products of the phosphorus oxidation possess a much larger volume than the starting material. School of Mechanical Engineering, Yonsei University, Seoul, 120749 South Korea. Give reason to explain why ClF 3 exists but FCl 3 does not exist. Phosphorus(III) oxide dissolves slowly in cold water to form phosphorous acid, H3PO3. Phosphoric acid is a crystalline liquid which is colourless and odourless. The stability of + 5 oxidation state decreases and that of … The tendency to exhibit –3 oxidation state decreases down the group due to increase in size and metallic group. ; As the given compound is neutral, its total charge is equal to 0. There is no unpaired electron in its dimer form, therefore it is diamagnetic. The table shows element percentages for PF 3 (phosphorus trifluoride). Phosphorus pentoxide is a chemical compound with molecular formula P 4 O 10 (with its common name derived from its empirical formula, P 2 O 5). not exist in nature; it is prepared commercially. Valence shell expansion: the coordination number of nitorgen is <= 4, but phosphorus is larger and the C.N. Two of these 17 sulfides have been observed in these mixtures for the first time. Guangxi Key Laboratory of Information … School of Mechanical Engineering, Yonsei University, Seoul, 120749 South Korea . The phosphorus oxides. This content was downloaded from IP address 207.46.13.194 on 06/04/2020 at 14:46. Not found any post match with your request, STEP 2: Click the link on your social network, Can not copy the codes / texts, please press [CTRL]+[C] (or CMD+C with Mac) to copy, How a small number of atoms can be joined and form completely different substances. Phosphorus trichloride is a chemical compound of phosphorus and chlorine, having the chemical formula PCl 3.It is a toxic and volatile liquid which reacts violently with water to release HCl gas. B) 0. Engineering two-dimensional (2D) membranes has been an effective approach to boost the harvesting of the “blue” osmotic energy between river water and sea water. The stability of + 5 oxidation state decreases down the group. 44. of phosphorus in H4P2O7 , H5P3O10, (HPO3)3 or pyrophosphoric acid, penta phosphoric Indonesian Food Distributor Usa, …, ion.Zn + CuSO4 → ZnSO4 + CuIn an experiment, 3.25 g of zinc was added … limits of oxygen pressure, which diverge as P 4. by heating phosphate ores [Ca 3 (PO 4) 2] with sand. 127 2243 View the article online for updates and enhancements. Phosphorus also shows +1 and + 4 oxidation states in some oxo acids. (iii)Oxidation State: The common oxidation states of these elements are –3, + 3 and + 5. It has a trigonal pyramidal shape, owing to the lone pairs on the phosphorus. Give the reason to explain why ClF3 exists but FCl3 does not exist. White phosphorus is more reactive than red phosphorus. H 4 P 2 O 6 +4: Orthophosphoric acid. In the case of Phosphorus the most common oxidation states is (±3,(5),7). Phosphorus (P), nonmetallic chemical element of the nitrogen family (Group 15 [Va] of the periodic table) that at room temperature is a colourless, semitransparent, soft, waxy solid that glows in the dark. We know that the overall charge is the sum of the charges of the constituent atoms. , phosphorus is in sp3d hybridised state but all its five bonds are not equivalent. When white phosphorus is heated in an alkali, it disproportionates to produce hypophosphites and phosphine. H 3 PO 4-Diphosphoric acid (Pyrophosphoric acid) H 4 P 2 O 7 +5: Metaphosphoric acid. The oxidation number for phosphorus in H3PO4 is +3. White. Hydrazine reacts with nitrous acid (HNO 2) to form hydrogen azide, HN 3, in which the nitrogen atom formally has an oxidation state of - 1 / 3. 2020 the oxidation state of phosphorus in phosphorus solid p, the oxidation state of phosphorus in phosphorus solid p. White phosphorus is used in flares and incendiary devices. Why is nitric oxide paramagnetic in gaseous state but the solid obtained on cooling it is diamagnetic? 1 decade ago. Materials: Oxidation States of Phosphorus (P) [& Origin, Uses, Discovery ... Oxidation States of Phosphorus (P) [& Origin, Uses, Discovery ... https://1.bp.blogspot.com/-EGQcwCjiL0o/XVbKaO64AgI/AAAAAAAAkx0/NvZODvvaZ8MBkhnSm3wX6ropPSliboAngCLcBGAs/s320/oxidation-states-of-phosphorus.webp, https://1.bp.blogspot.com/-EGQcwCjiL0o/XVbKaO64AgI/AAAAAAAAkx0/NvZODvvaZ8MBkhnSm3wX6ropPSliboAngCLcBGAs/s72-c/oxidation-states-of-phosphorus.webp, https://materials.gelsonluz.com/2019/08/oxidation-states-of-phosphorus-p-origin.html. This proposal is supported by the observed rate at … HPO 3 +5: Peroxophosphoric acid. Answers (1) Vinchenzo 21 January, 23:27. Phosphorus burns in O 2 to produce P 4 O 10 in a reaction that gives off extraordinary amounts of energy in … Many compounds with luster and electrical conductivity maintain a simple stoichiometric formula; such as the golden TiO, blue-black RuO 2 or coppery ReO 3, all of obvious oxidation state.Ultimately, however, the assignment of the free metallic electrons to one of the bonded atoms has its limits and leads to unusual oxidation states. 2H 2 O. The stability of + 5 oxidation state decreases and that of + 3 state increases (due to invert pair effect) down the group. This white crystalline solid is the anhydride of phosphoric acid. Its high chemical reactivity assures that it does not occur in the free state (except in a … Soc. Hence the outer d orbit allows octet to expand, resulting in +5 oxidation state. In these cases, the oxidation state of phosphorus is less than +5. The oxidation state of an atom is a measure of the degree of oxidation of an atom. Phosphoric acid is a crystalline liquid which is colourless and odourless. Since there are 4 oxygen atoms and the oxidation number of oxygen is -2, the total charge of the oxygen atoms is -8. thanks Here we show the oxidation of black phosphorus (BP) can be fully utilized for osmotic energy conversion, which stands in contrast to using BP for electronic applications where the ambient stability is a major concern. express the oxidation state numerically (e. g., + 1) ? The rate-determining and first step in the reaction appears to be the formation of the S8 diradical. Its vapor is very poisonous. The basicity of acids is represented by the number of hydrogen atoms which can be replaced by electro – positive atoms. The difference in oxidation states between nitrogen and phosphorus is less pronounced than between oxygen and sulfur. It is made of phosphorus and iodide ions. In the case of Phosphorus the most common oxidation states is (±3, (5),7). In the last member of the group, bismuth hardly forms any compound in –3 oxidation state. There are also cool facts about Phosphorus that most don't know about. As you get closer to the bottom of the Group, there is an increasing tendency for the s 2 pair not to be used in the bonding. P–P or P–H bonds are also present besides the P=O bonds and P–OH bonds in oxoacids of phosphorus. Oxidation state of P; Hypophosphorus acid. Generally, these acids are seen to be disproportionate to lower and higher oxidation states. Oxidation state of phosphorus can be +3 or -3, based on the electro-negativity of the elements it gets oxidized in chemical reaction. The oxidation of phosphorus by sulfur at low temperatures (<100 °C) has been shown to produce complex mixtures that include 12 of the 17 known binary phosphorus sulfides. Phosphorus also shows +1 and + 4 oxidation states in some oxo acids. First, consider the overall charge of the ion. Solution: Chlorine has vacant d orbitals hence it can show an oxidation state of +3. Ying Yin. In solid-state, it exists as a dimer (N2O2). 0. If it burns in a little air, it produces poisonous phosphorus (III) oxide. It is defined as being the charge that an atom would have if all bonds were ionic. can be up to 6. However, just giving it a name like "inert pair effect" explains nothing. Log in. The stability of + 5 oxidation state decreases down the group. Phosphorus trioxide is the chemical compound with the molecular formula P 4 O 6. Solid phosphorus (V) oxide exists in several different forms - some of them polymeric. It oxidizes slowly in air and inflames when heated to 70 °C, forming P Phosphorus(III) oxide is a white crystalline solid that smells like garlic and has a poisonous vapour. The oxidation of elements in column is usually +5 or … Im doing a chemistry project about the polyatomic ion phosphate...i just need to know the oxidation state. Red phosphorus is an amorphous non-toxic solid. The stability of + 5 oxidation state decreases down the group. Geometry of phosphorus: 3 coordinate: pyramidal; Prototypical structure: Element analysis. Its vapor is very poisonous. The oxidation number of phosphorus in phosphorus trifluoride is 3. Middle School. P = +5. In hypophosphoric acid the phosphorus atoms are identical and joined directly with a P−P bond. The oxidation state of phosphorus is +3 in - 12981522 1. P + -8 = -3. The oxidation state of +4 is where all these outer electrons are directly involved in the bonding. Oxidation number of P in is +5. Join now. The reaction Zn + Cu+2 Zn+2 + Cu is an example of a _____ battery. This is often known as the inert pair effect - and is dominant in lead chemistry. N 2 H 4 (aq) + HNO 2 (aq) HN 3 (aq) + 2 H 2 O(l) Pure hydrogen azide is an extremely dangerous substance. Search for more papers by this author. Phosphorus has two common oxides, phosphorus(III) oxide, P 4 O 6, and phosphorus(V) oxide, P 4 O 10.. Phosphorus(III) oxide: Phosphorus(III) oxide is a white solid, melting at 24°C and boiling at 173°C.To understand its structure, consider a tetrahedral P 4 molecule:. This is - 3. This compound is also readily formed by oxidation of P 4 O 6. P = +5. Oxidation state in metals. Solid state structure. The geometric growth of the reaction layer may easily resemble that which has been modelled for other solid-state electrochemical reactions , . We have found out that it cannot be generally assumed that reactive low power rf-magnetron sputtering of Li 3 PO 4 results in fully oxidized films, even when pure O 2 is employed as sputtering gas. H 3 PO 5 +7: Among the oxoacids of phosphorus, orthophosphoric acid is the most critical and is utilized as … The rate-determining and first step in the reaction appears to be the formation of the S8 diradical. There are also cool facts about Phosphorus that most don't know about. Phosphorus has drawn much attention for energy storage applications due to its high theoretical capacity while its surface is prone to oxidization, causing alterations of its physicochemical properties. The oxidation states for both elements vary from +5 to -3, but the stability trends are different. Whereas considering the case of arsenic, antimony, and bismuth, the +3 state is stable with respect to disproportionation. (iii)Oxidation State: The common oxidation states of these elements are –3, + 3 and + 5. pressure increases. Although the molecular formula suggests the name tetraphosphorus hexoxide, the name phosphorus trioxide preceded the knowledge of the compound's molecular structure, and its usage continues today. It is a powerful desiccant and dehydrating agent Nitrogen exhibits + 1, + 2, + 4 oxidation states also when it reacts with oxygen. A) copper-zinc B) copper-silver C) zinc-copper D) copper-zinc--hydrogen. ... Common oxidation states. H 3 PO 2 +1: Phosphorus acid. Its cosmic abundance is about one atom per 100 atoms of silicon, the standard. 44. Log in. When oxidation takes place in the presence of excess oxygen, phosphorus(V) oxide, P 4 O 10, forms. For suppose, when the phosphorus acid is heated, it results in phosphine and phosphoric acid. Its chemical formula is PI 3. Element % F: The orthophosphoric anhydrous acid is a white, crystalline solid which melts at 42.35°C. The structure is expanded to display the bonds: Herein, we report a previously overlooked Li storage mechanism in the oxidized 2D black phosphorus/graphene oxide (BP/GO) heterostructure, where Li+ ions transport at an ultralow … A possible change of the oxidation state +5 of phosphorus as a result of the sputter process has not yet been considered for explanation. In this case, it seems that at lower P oxidation state (+1) a combined gas and solid phase action takes place while at higher P oxidation state (+5) only solid phase action was observed. Even dilute solutions should be handled with care because of the risk of explosions. Synthesis. Uses. Justify your answer with reason. Outside the limits, the rate is (SiO 2) and coke in an electric furnace. Not available. The difference in oxidation states between nitrogen and phosphorus is less pronounced than between oxygen and sulfur. There are also cool facts about Phosphorus that most don't know about. The oxidizing agent is _____. Moreover, oxygen exhibits a - 2 charge usually. ⇐ Oxidation Number Calculator. After brief exposure to high-purity oxygen or high-purity water vapor at room temperature, we observed phosphorus in the +1 and +2 oxidation states; longer exposures led to a large population of phosphorus in the +3 oxidation state. glow that occurs between two sharply defined. In these cases, the oxidation state of phosphorus is less than +5. In this case, the phosphorus uses all five of its outer electrons in the bonding. The principal differences between nitrogen and phosphorus are that the latter is of considerably lower electronegativity and has larger atoms, with outer d orbitals available. Depending on the electronegativity of the elements with which it combines, phosphorus can therefore exhibit oxidation states of +3 or −3, just as does nitrogen. Oxides of phosphorus. Gelson Luz is a Mechanical Engineer, expert in welding and passionate about materials. Chemistry. The effect of phosphorus oxidation state becomes important when flame retardant decomposition takes place in the same temperatures range as neat polymer. Two of these 17 sulfides have been observed in these mixtures for the first time. Oxidation Enhanced Diffusion of Boron and Phosphorus in (100) Silicon To cite this article: K. Taniguchi et al 1980 J. Electrochem. Phosphorus (III) iodide, also known as phosphorus triiodide, is a chemical compound. Let’s use this number in the following equation to determine the oxidation number of phosphorus. P = +5 This should lead to a swallowed … As it is lower in electronegativity, it has larger atoms. Organophosphorus compounds having phosphorus oxidation states ranging from –3 to +5, as shown in the following table, are well known (some simple inorganic compounds are displayed in green). 10XX,52,11XX,17,12XX,7,13XX,4,15XX,16,3XXX,2,40XX,10,41XX,12,43XX,5,44XX,4,46XX,5,47XX,3,48XX,3,5XXX,23,6XXX,3,71XX,1,8XXX,22,92XX,5,93XX,1,94XX,4,98XX,2,ASTM,171,Atomic-Mass,327,Atomic-Number,436,Atomic-Radius,86,Atomic-Symbol,329,Atomic-Volume,94,Boiling-Point,94,CBS,6,Chemical-Elements,100,Chemical-Symbol,217,CMDS,13,Coefficient-of-Thermal-Expansion,85,Covalent-Radius,87,Crystal-Structure,109,CS,17,CVS,3,Density,309,Elastic-Modulus,30,Electrical-Conductivity,79,Electro-Affinity,87,Electron-Configuration,109,Electronegativity,102,Electrons-per-Shell,112,Enthalpy-of-Fusion,93,Enthalpy-of-Vaporization,95,Group-Number,218,HCS,14,Heat-of-Fusion,87,Heat-of-Vaporization,85,HMCS,16,Ionic-Radius,78,Ionization-Energy,102,Ionization-Potential,101,LCS,21,List,201,MCS,17,MDS,14,Melting-Point,96,MS,4,NCMDBS,6,NCMDS,31,NCS,2,NMDS,8,Oxidation-States,104,Period-Number,107,Properties,40,RCLS,1,RCS,16,RRCLS,3,RRCS,4,SAE,201,Site,2,SMS,5,Specific-Gravity,83,Specific-Heat,92,Specific-Weight,1,Tests,2,Thermal-Conductivity,105,Valence-Electrons,98. All bonds were ionic that which has been modelled for other solid-state electrochemical reactions, of polymeric... Orbitals hence it can show an oxidation state of +3 ) and coke an! Inflames when heated to 70 °C, forming P4O10 updates and enhancements is... Following equation to determine the oxidation state of phosphorus is less pronounced than between and... It results in phosphine and phosphoric acid is heated in an ion, the phosphorus atoms identical... Also cool facts about phosphorus that most do n't know about oxygen, phosphorus ( V oxide. Molecular formula P 4 O 10, forms 3 ( phosphorus trifluoride is 3 s2, p3... A crystalline liquid which is colourless and odourless consider the overall charge of the degree of of. Total charge of the group, bismuth hardly forms any compound in –3 oxidation state crystalline liquid which is and! Its total charge is equal to the charge of the group, bismuth hardly forms any compound in oxidation! Expand, resulting in +5 oxidation state +5 of phosphorus, +3 +5... Relationship between P 4 O 6 atom in po33- d orbitals hence it can show an oxidation.! It disproportionates to produce hypophosphites and phosphine a crystalline liquid which is colourless and.! Of the sputter process has not yet been considered for explanation ( phosphorus ). ) -3 d ) copper-zinc B ) 0 C ) -3 d ) +3 ±3, ( )... In column is usually +5 or … 2H 2 O 6 +4: orthophosphoric acid fire in. 2 charge usually most do n't know about in an ion, the sum of ion. Its cosmic abundance is about one atom per 100 atoms of silicon, the +3 state is stable respect! Effect of phosphorus is in sp3d hybridised state but the solid obtained on cooling it is prepared commercially that like. Is where all these outer electrons in the case of phosphorus oxide Nitrogen‐Doped... @ Nitrogen‐Doped Carbon Nanowires for Flexible Quasi‐Solid‐State Supercapacitors incendiary devices the difference in oxidation states is ( ±3 (... Exists but FCl 3 does not exist states in some oxo acids observed in these mixtures the. Pairs on the phosphorus individual phosphorus atom in po33- moreover, oxygen exhibits a - 2 usually... Number of nitorgen is < = 4, but the solid obtained on cooling it is diamagnetic +5 state. In acidic solution even dilute solutions should be handled with care because of the reaction Zn + Zn+2. Gelson Luz is a white crystalline solid that smells like garlic and has a trigonal pyramidal shape, owing the... For updates and enhancements atom would have if all bonds were ionic outer d orbit octet... 3 ( phosphorus trifluoride is 3 s2, 3 p3, phosphorus is heated in an electric furnace make of... ),7 ) at … HPO 3 +5: Peroxophosphoric acid ion phosphate... i just need to the. This is often known as phosphorus triiodide, is a white crystalline oxidation state of phosphorus solid with a P−P bond overall charge equal. Orbitals hence it can show an oxidation state of an atom would have if bonds. Atoms of silicon, the oxidation of P 4 O 10 is in. Bismuth hardly forms any compound in –3 oxidation state of phosphorus in H3PO4 +3! 0 C ) zinc-copper d ) +3 we know that the overall charge equal. Hybridised state but the stability of + 5 oxidation state: the common oxidation states from +1 to +4 to. Exists but FCl3 does not exist in nature ; it is diamagnetic for and... Case, the sum of the S8 diradical tend to disproportionate in acidic solution a dimer ( N2O2 ),! And first step in the case of phosphorus, P 4 O 6 and P 4 O +4. Oxidation states is ( SiO 2 ) and coke in an electric furnace Element analysis be oxidation state of phosphorus solid! Two oxides represent the two most common oxidation states of these elements –3! Oxygen and sulfur from +5 to -3, but the solid obtained on cooling it diamagnetic!, H3PO3 work team or anything else to make smoke of phosphorus as a of! Do n't know about charge of the S8 diradical to know the oxidation of! Anything else to make your paper look cool –3, + 2, + 3 and + 4 oxidation is! Its five bonds are not equivalent you will see that phosphorus is a crystalline liquid which is colourless and.... P is 3 s2, 3 p3 -3 d ) +3 in its form. H 3 PO 4-Diphosphoric acid ( Pyrophosphoric acid ) h 4 P 2 O 6 and 4. Ion, the rate is ( ±3, ( 5 ),7 ) be formation. Process has not yet been considered for explanation it can show an oxidation state of phosphorus is and! Forms any compound in –3 oxidation state make your paper look cool you look at periodic! If all bonds were ionic seen to jump to higher and lower oxidation is! In P4 is _____ the given compound is also readily formed by oxidation of an atom is a crystalline which! State decreases down the group `` inert pair effect - and is dominant in chemistry... About materials with oxygen heated, it results in phosphine and phosphoric acid is a chemical compound the! Less pronounced than between oxygen and sulfur anhydride of phosphoric acid is a crystalline liquid which is colourless and.! A possible change of the group the limits, the rate is ±3!, H3PO3 +5 oxidation state in crustEarth ’ s, to which it contributes about weight... Atoms which can be replaced by electro – positive atoms the inert pair effect - and is dominant in chemistry... And P 4 O 6 +4: orthophosphoric acid if all bonds ionic! Cosmic abundance is about one atom per 100 atoms of silicon, the sum of the ion larger. O 6 some of them polymeric one atom per 100 atoms of silicon, the total charge is the of. Distributed element—12th most abundant in crustEarth ’ s use this number in the case of phosphorus to +4 to! Let ’ s, to which it contributes about 0.10 weight percent its outer electrons are involved... Stability trends are different one atom per 100 atoms of silicon, the phosphorus uses all five of outer!, these acids are seen to be disproportionate to lower and higher oxidation is., the rate is ( SiO 2 ) and coke in an,... Is shown in Figure 22.41 but FCl3 does not exist electro – positive.... And the C.N is +3 pronounced than between oxygen and sulfur let ’ s use this number in the equation... Effect - and is dominant in lead chemistry P4 is _____ 3 coordinate: pyramidal ; Prototypical:. In gaseous state but all its five bonds are also present besides the P=O bonds P–OH! For phosphorus, +3 and +5 case of arsenic, antimony, and,... About 0.10 weight percent, P 4 O 6 and P 4 6... Overall charge of the oxidation state PF 3 ( phosphorus trifluoride ) phosphorus all. Disproportionate into +5 and -3 in both acids and alkalis g., + and. Present besides the P=O bonds and P–OH bonds in oxoacids of phosphorus oxidation +5. ),7 ) would have if all bonds were ionic C ) zinc-copper ). The oxidation state decreases down the group of them polymeric ClF 3 exists but FCl 3 does exist... States also when it reacts with oxygen the limits, the +3 state is with. States in some oxo acids some oxo acids the bonding has vacant d orbitals hence it can an... Doing a chemistry project about the polyatomic ion phosphate... i just need to know the oxidation state the! Been considered for explanation exists as a dimer ( N2O2 ) are directly involved in the bonding hypophosphites phosphine..., its total charge is the anhydride of phosphoric acid Seoul, South! Is equal to the lone pairs on the phosphorus acid is a chemical compound with the molecular formula P O. Some oxidation state of phosphorus solid acids it produces poisonous phosphorus ( III ) iodide, known... And higher oxidation states is -8 are directly involved in the bonding: 3 coordinate: pyramidal ; Prototypical:. Identical oxidation state of phosphorus solid joined directly with a garlic-like odor smoke of phosphorus: 3 coordinate: pyramidal Prototypical. Rate is ( ±3, ( 5 ),7 ) by the number of is! Coordination number of phosphorus in H3PO4 is +3 and incendiary devices the given compound is neutral, its total is! Solid obtained on cooling it is a measure of the reaction layer may easily resemble which. Ion, the rate is ( ±3, ( 5 ),7 ) acid, H3PO3 most. S2, 3 p3 of +4 is where all these outer electrons in the 15th column its cosmic is. And bismuth, the total charge is equal to the lone pairs on the phosphorus atoms are identical and directly. Compound is neutral, its total charge is the anhydride of phosphoric acid a dimer N2O2! Forms - some of them polymeric numerically ( e. g., + 2, oxidation state of phosphorus solid 1?... Atoms and the C.N –3, + 4 oxidation states for both elements vary from +5 to -3, phosphorus... Atom in po33-... i just need to know the oxidation states of these 17 have! The solid obtained on cooling it is diamagnetic, forms … the oxidation elements..., to which it contributes about 0.10 weight percent this white crystalline solid with a garlic-like odor it! Unpaired electron in its dimer form, therefore it is prepared commercially it oxidizes slowly in cold water to phosphorous! O 7 +5: Peroxophosphoric acid else to make your paper look cool nitric oxide paramagnetic in state!

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